I think (though haven't tested) that you can just do $location = $response->header('Location') to get it (or it's set to null if it's missing).
https://github.com/laravel/framework/blob/5.2/src/Illuminate/Http/Request.php#L512
Edit: doh! just noticed that was the request rather than the response. Sorry! Try doing a dd($response) to see what's there maybe?
Edit2 : apparently you can do things like :
$this->assertEquals('application/json',
$response->headers->get('Content-Type'));